Reduction of carbon dioxide and organic carbonyls by hydrosilanes catalysed by the perrhenate anion

5 years ago

Reduction of carbon dioxide and organic carbonyls by hydrosilanes catalysed by the perrhenate anion

Mirza Cokoja, Julian T. C. Wennmacher, Catherine Weetman, Fritz E. Kuhn, Markus Drees, Jason B. Love, Danny S. Morris

A simple quaternary ammonium perrhenate salt catalyses the hydrosilylation of aldehydes, ketones, and carbon dioxide, and the methylation of amines using carbon dioxide. DFT calculations show that a perrhenate hypervalent silicate interacts directly with CO₂.

Publisher URL: http://feeds.rsc.org/~r/rss/cy/~3/AC9BUA3N1cc/C7CY00772H

DOI: 2017/CY/C7CY00772H

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