3 years ago

Interaction of gem-Difluorinated Iodides with Silyl Enol Ethers Mediated by Photoredox Catalysis

Interaction of gem-Difluorinated Iodides with Silyl Enol Ethers Mediated by Photoredox Catalysis
Alexander D. Dilman, Marina I. Struchkova, Vitalij V. Levin, Vladimir A. Kokorekin, Grigory N. Chernov
A method for the synthesis of β,β-difluorinated ketones by coupling of α,α-difluorinated iodides with silyl enol ethers is described. The reaction is performed in the presence of iridium(III) photocatalysts under the irradiation with 400 nm light emitting diodes.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/adsc.201700423

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