Advanced Synthesis and Catalysis
Advanced Synthesis and Catalysis
4 years ago

Calcium(II)-Catalyzed Alkenylation of N-Acyliminiums and Related Ions with Vinylboronic Acids

Calcium(II)-Catalyzed Alkenylation of N-Acyliminiums and Related Ions with Vinylboronic Acids
Vincent Gandon, Chenxiao Qi, David Lebœuf
Efficient C−C bond-forming reactions between N,O-acetals and vinylboronic acids were achieved via a calcium(II)-catalyzed formation of a N-acyliminium intermediate or a related ion. This strategy can give a rapid access to a wide variety of alkenyl-functionalized nitrogen-containing compounds in good to excellent yields under simple reaction conditions.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/adsc.201700214

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