Advanced Synthesis and Catalysis
Advanced Synthesis and Catalysis
5 years ago

Palladium-Catalyzed Regioselective Allylation of Chloromethyl(hetero)arenes with Allyl Pinacolborate

Palladium-Catalyzed Regioselective Allylation of Chloromethyl(hetero)arenes with Allyl Pinacolborate
Ming Bao, Aziz Ullah, Sheng Zhang, Yoshinori Yamamoto
The palladium-catalyzed regioselective allylation reaction between chloromethyl(hetero)arenes and allyl pinacolborate is reported in this work. Chloromethylarenes smoothly reacted with allyl pinacolborate, producing para-allylated dearomatization products or para-allylated arenes in satisfactory to good yields. 2-(Chloromethyl)thiophenes and 2-(chloromethyl)furans bearing substituents on the 5-positions also smoothly reacted with allyl pinacolborate, producing the 5-allylated dearomatization products in satisfactory yields.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/adsc.201700350

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