5 years ago

Mo2B4O9—Connecting Borate and Metal-Cluster Chemistry

Mo2B4O9—Connecting Borate and Metal-Cluster Chemistry
Hellmut Eckert, Martin K. Schmitt, Amadeus-Samuel Tragl, Dirk Johrendt, Oliver Janka, Christopher Benndorf, Richard Weihrich, Hubert Huppertz, Marcos de Oliveira, Florian Pielnhofer, Bastian Joachim, Rainer Pöttgen
Two fields are united in Mo2B4O9, the first borate compound incorporating transition-metal clusters into its crystal structure. It thus constitutes the hitherto unknown interface between two previously separated fields of research—borate and metal cluster chemistry. In their Communication http://doi.org/10.1002/anie.201701891 H. Huppertz and co-workers show how the planned reduction of a reagent in a high-pressure experiment smoothed the way to this novel substance class.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201703990

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