3 years ago

Intra- versus Intermolecular Hydrogen Bonding: Solvent-Dependent Conformational Preferences of a Common Supramolecular Binding Motif from 1H NMR and Vibrational Circular Dichroism Spectra

Intra- versus Intermolecular Hydrogen Bonding: Solvent-Dependent Conformational Preferences of a Common Supramolecular Binding Motif from 1H NMR and Vibrational Circular Dichroism Spectra
Daniel P. Demarque, Christian Merten
Invited for the cover of this issue are Daniel P. Demarque and Christian Merten from Ruhr University in Bochum, Germany. The image depicts a DMSO-solvated 2,6-pyridinediyl-dialkylamide, the model system used in their study to investigate solute-solvent driven conformational changes. Read the full text of the article at 10.1002/chem.201703643. “The selected model system suggests the occurrence of much more dynamic binding situations in solution-phase supramolecular chemistry than potentially expected from NMR-spectroscopic or crystallographic pictures.” Read more about the story behind the cover in the Cover Profile and about the research itself on page ▪▪ ff. (DOI: 10.1002/chem.201703643).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201704987

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