3 years ago

Cp*RhIII-Catalyzed C–H Amidation of Ferrocenes

Cp*RhIII-Catalyzed C–H Amidation of Ferrocenes
Shu-Li You, Qing Gu, Shao-Bo Wang
Amidation of N-containing heteroaryl ferrocenes with 1,4,2-dioxazol-5-ones as the amidated reagents was achieved via a Rh-catalyzed direct C–H functionalization reaction. Under mild reaction conditions, a wide range of N-ferrocenyl amides were obtained in up to 99% yield. Transformations of the amide group were also feasible.

Publisher URL: http://dx.doi.org/10.1021/acs.organomet.7b00691

DOI: 10.1021/acs.organomet.7b00691

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