3 years ago

Oxidation of C-H compounds with peroxides catalyzed by polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks: A review

Oxidation of C-H compounds with peroxides catalyzed by polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks: A review
Polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks synthesized in recent years turned out to be efficient catalysts in oxidation of organic compounds with peroxides: H2O2, tert-butyl hydroperoxide (TBHP), meta-chloroperoxybenzoic acid (MCPBA). This brief review describes oxygenations by peroxides of alkanes to alkyl hydroperoxides, alcohols and ketones and benzene to phenol as well as oxidation of alcohols to the corresponding ketones. Some reactions with MCPBA occur stereoselectively.

Publisher URL: www.sciencedirect.com/science

DOI: S0022328X17302930

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.