Organic Letters
Organic Letters
5 years ago

Synthesis of Functionalized Indenones via Rh-Catalyzed C–H Activation Cascade Reaction

Synthesis of Functionalized Indenones via Rh-Catalyzed C–H Activation Cascade Reaction
Zhanxiang Liu, Ningning Lv, Yue Liu, Zhengkai Chen, Yuhong Zhang
An efficient and expeditious protocol for the synthesis of diverse difunctionalized indenones through rhodium-catalyzed C–H activation and multistep cascade reaction of benzimidates and alkenes has been developed. The transformation involves the cleavage and formation of multiple bonds in one pot under mild reaction conditions, and Mn(OAc)2 plays an important role in the reaction.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b00906

DOI: 10.1021/acs.orglett.7b00906

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