3 years ago

Mixed Valency in a 3D Semiconducting Iron–Fluoranilate Coordination Polymer

Mixed Valency in a 3D Semiconducting Iron–Fluoranilate Coordination Polymer
Keith S. Murray, Deanna M. D’Alessandro, Guy N. L. Jameson, Timothy A. Hudson, Richard Robson, Brendan F. Abrahams, Ryuichi Murase, Ashley L. Sutton, Casey G. Davies, Boujemaa Moubaraki
The synthesis, structure, and characterization of a pair of coordination networks of composition (NBu4)2[M2(fan)3] (fan = fluoranilate; M = Fe, Zn) is described. In each case there are two interpenetrating enantiomeric networks in which octahedral metal centers are linked by fluoranilate ligands. While the two compounds are structurally similar, there are significant differences in the properties of the two materials that can be attributed to the mixed valency in the semiconducting compound (NBu4)2[Fe2(fan)3].

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01038

DOI: 10.1021/acs.inorgchem.7b01038

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