4 years ago

Mixed Valency in a 3D Semiconducting Iron–Fluoranilate Coordination Polymer

Mixed Valency in a 3D Semiconducting Iron–Fluoranilate Coordination Polymer
Keith S. Murray, Deanna M. D’Alessandro, Guy N. L. Jameson, Timothy A. Hudson, Richard Robson, Brendan F. Abrahams, Ryuichi Murase, Ashley L. Sutton, Casey G. Davies, Boujemaa Moubaraki
The synthesis, structure, and characterization of a pair of coordination networks of composition (NBu4)2[M2(fan)3] (fan = fluoranilate; M = Fe, Zn) is described. In each case there are two interpenetrating enantiomeric networks in which octahedral metal centers are linked by fluoranilate ligands. While the two compounds are structurally similar, there are significant differences in the properties of the two materials that can be attributed to the mixed valency in the semiconducting compound (NBu4)2[Fe2(fan)3].

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01038

DOI: 10.1021/acs.inorgchem.7b01038

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.