3 years ago

Novel Xanthate Complexes for the Size-Controlled Synthesis of Copper Sulfide Nanorods

Novel Xanthate Complexes for the Size-Controlled Synthesis of Copper Sulfide Nanorods
James Raftery, Paul D. McNaughter, Egid B. Mubofu, Inigo Vitorica-Yrezabal, Geradius Deogratias, Peter D. Matthews, Mundher Al-Shakban, Paul O’Brien
We present a simple route to monodisperse copper sulfide nanocrystals by the hot injection of a series of novel copper(I) xanthate single-source precursors [(PPh3)2Cu(S2COR)] (R = isobutyl, 2-methoxyethyl, 2-ethoxyethyl, 1-methoxy-2-propyl, 3-methoxy-1-butyl, and 3-methoxy-3-methyl-1-butyl), whose crystal structures are also reported. We show that the width of the obtained nanorods is dependent on the length of the xanthate chain, which we rationalize through a computational study.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01288

DOI: 10.1021/acs.inorgchem.7b01288

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