3 years ago

Two New Sandwich-Type Manganese {Mn5}-Substituted Polyoxotungstates: Syntheses, Crystal Structures, Electrochemistry, and Magnetic Properties

Two New Sandwich-Type Manganese {Mn5}-Substituted Polyoxotungstates: Syntheses, Crystal Structures, Electrochemistry, and Magnetic Properties
Pedro de Oliveira, Sadafumi Nishihara, Imran Khan, Chisato Kato, Masahiro Sadakane, Rakesh Gupta, Firasat Hussain, Katsuya Inoue, Katsuya Ichihashi, Israël M. Mbomekallé, A. Martin Bossoh
Two new manganese-containing polyoxometalates (Mn-POMs) were synthesized from the reaction of the lacunary precursor Na9[B-α-XW9O33] (X = AsIII and SbIII) with MnII cations and bpy ligands. Single-crystal X-ray diffraction (SCXRD) investigations revealed a structural similarity of Mn-POMs. The polyoxometalates were well characterized by SCXRD, electrospray ionization mass spectrometry, electrochemistry, and magnetism.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.6b02994

DOI: 10.1021/acs.inorgchem.6b02994

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