Inorganic Chemistry
Inorganic Chemistry
5 years ago

Two New Sandwich-Type Manganese {Mn5}-Substituted Polyoxotungstates: Syntheses, Crystal Structures, Electrochemistry, and Magnetic Properties

Two New Sandwich-Type Manganese {Mn5}-Substituted Polyoxotungstates: Syntheses, Crystal Structures, Electrochemistry, and Magnetic Properties
Pedro de Oliveira, Sadafumi Nishihara, Imran Khan, Chisato Kato, Masahiro Sadakane, Rakesh Gupta, Firasat Hussain, Katsuya Inoue, Katsuya Ichihashi, Israël M. Mbomekallé, A. Martin Bossoh
Two new manganese-containing polyoxometalates (Mn-POMs) were synthesized from the reaction of the lacunary precursor Na9[B-α-XW9O33] (X = AsIII and SbIII) with MnII cations and bpy ligands. Single-crystal X-ray diffraction (SCXRD) investigations revealed a structural similarity of Mn-POMs. The polyoxometalates were well characterized by SCXRD, electrospray ionization mass spectrometry, electrochemistry, and magnetism.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.6b02994

DOI: 10.1021/acs.inorgchem.6b02994

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.