3 years ago

Intermediate-Valence Ytterbium Compound Yb4Ga24Pt9: Synthesis, Crystal Structure, and Physical Properties

Intermediate-Valence Ytterbium Compound Yb4Ga24Pt9: Synthesis, Crystal Structure, and Physical Properties
Yu-Han Wu, Walter Schnelle, Lev Akselrud, Yurii Prots, Yu-Ting Wang, Yuki Utsumi, Olga Sichevych, Ulrich Burkhardt, Yuri Grin, Matej Bobnar, Marcus Schmidt, Liu Hao Tjeng, Ku-Ding Tsuei, Mauro Coduri
The monoclinic structure of Yb4Ga24Pt9 (space group C2/m) consists of pseudotrigonal slabs arranged in the sequence ABABB. An intermediate valence for ytterbium species of ∼2.5 was established from hard X-ray photoelectron spectra, magnetic susceptibility measurements, and temperature-dependent X-ray diffraction.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01530

DOI: 10.1021/acs.inorgchem.7b01530

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