4 years ago

Intercalation of Primary Alcohols into Layered Titanoniobates

Intercalation of Primary Alcohols into Layered Titanoniobates
Maarit Karppinen, Chris I. Thomas
Primary alcohols have been intercalated between the layers of HTiNbO5 for the first time via a two-step process. As alcohols are less basic than amines, they are unable to go via the one-step acid−base mechanism, requiring instead an amine intermediate. Intercalation causes a significant expansion of the unit cell followed by XRD. This shows how alcohols can be used to influence the interlayer space of oxide sheets in functional layered oxide ceramics.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01135

DOI: 10.1021/acs.inorgchem.7b01135

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