3 years ago

Copper-Catalyzed Asymmetric Borylallylation of Vinyl Arenes

Copper-Catalyzed Asymmetric Borylallylation of Vinyl Arenes
Do Hyun Ryu, Jung Tae Han, Jaesook Yun, Namhyeon Kim
A copper-catalyzed, enantioselective method for the borylallylation of vinyl arenes is reported. The reaction produces enantioenriched and functionalized organoboron compounds by sequentially incorporating boryl and allyl groups onto the C═C bond of vinyl arenes. Copper-catalyzed borylative coupling of vinyl arenes with allyl phosphates successfully proceeds in a regio- and enantioselective manner in the absence of a palladium cocatalyst.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b03022

DOI: 10.1021/acs.orglett.7b03022

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