4 years ago

Molybdenum Oxide Nitrides of the Mo2(O,N,□)5 Type: On the Way to Mo2O5

Molybdenum Oxide Nitrides of the Mo2(O,N,□)5 Type: On the Way to Mo2O5
Oliver Niehaus, Martin Lerch, Ute Kolb, Rainer Pöttgen, Dominik Weber, Nils Becker, Tatiana E. Gorelik, Hans Boysen, Anatoliy Senyshyn, Sean P. Culver, Manop Huber, Thorsten Ressler, Christian Schwickert, Richard Dronskowski, Artem M. Abakumov
Blue-colored Mo2(O,N,□)5-type oxide nitrides with an average oxidation state of +5 for molybdenum were synthesized. They are structurally related to VNb9O24.9-type phases; the magnetic behavior is in agreement with compounds exhibiting MoVO6 units. The results demonstrate the possibility of a future synthesis of the binary oxide Mo2O5. On the basis of these findings, a tentative suggestion on the crystal structure of Mo2O5, backed by electronic-structure and phonon calculations from first principles, is given.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00551

DOI: 10.1021/acs.inorgchem.7b00551

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