3 years ago

Redox Interconversion of Non-Oxido Vanadium Complexes Accompanied by Acid–Base Chemistry of Thiol and Thiolate

Redox Interconversion of Non-Oxido Vanadium Complexes Accompanied by Acid–Base Chemistry of Thiol and Thiolate
Jyun-An Yan, Cheng-Yun Tsai, Ya-Ho Chang, Hua-Fen Hsu, Gene-Hsiang Lee, Chun-Gang Luo, Yu-Sen Chen, Chiao-Ling Lyu
A class of non-oxido vanadium thiolates is isolated and characterized. The system is robust and can undergo two-electron and two-proton reversible transformations. The work shows the versatile nature of non-oxido vanadium complexes in terms of oxidation state and coordination number with the structural motif remaining intact. The thiol/thiolate donor acts as a mediator through acid−base chemistry to facilitate the change of the ligation environment of the vanadium center.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01040

DOI: 10.1021/acs.inorgchem.7b01040

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