Inorganic Chemistry
Inorganic Chemistry
5 years ago

Large Differences in the Optical Spectrum Associated with the Same Complex: The Effect of the Anisotropy of the Embedding Lattice

Large Differences in the Optical Spectrum Associated with the Same Complex: The Effect of the Anisotropy of the Embedding Lattice
Pablo García-Fernández, Juan María García-Lastra, José Antonio Aramburu, Miguel Moreno
Understanding the huge difference in the d−d transitions (up to 1.27 eV) in square-planar CuF42− units in CaCuF4 material and center II in Cu2+-doped Ba2ZnF6 requires to consider the anisotropic electric field due to the ions of each lattice.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00932

DOI: 10.1021/acs.inorgchem.7b00932

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