3 years ago

Conformational Landscapes of Metal(II) Porphyrinato, Chlorinato, and Morpholinochlorinato Complexes

Conformational Landscapes of Metal(II) Porphyrinato, Chlorinato, and Morpholinochlorinato Complexes
Matthias Zeller, Alexander L. Ticho, Christian Brückner, Meenakshi Sharma, Lalith Samankumara
The conversion of meso-tetraarylporphyrin to its corresponding 2,3-dimethoxychlorin and the subsequent expansion of the pyrroline moiety to a morpholine moiety renders the macrocycle increasingly more conformationally flexible, as shown by a comparison of the solid-state conformations of the macrocycles as their free bases and metal complexes (M = Ni2+, Cu2+, Zn2+, Pd2+, Ag2+). The conformation is also reflected in their differing UV−vis spectra.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00799

DOI: 10.1021/acs.inorgchem.7b00799

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