3 years ago

Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C–H Functionalizations

Trans-Metal-Trapping Meets Frustrated-Lewis-Pair  Chemistry: Ga(CH2SiMe3)3-Induced C–H Functionalizations
Alan R. Kennedy, Eva Hevia, Marina Uzelac
Steric mismatches between GaR3 and LiTMP or N-heterocyclic carbenes switch on cooperative effects that enable the activation of organic molecules via trans-metal-trapping and frustrated-Lewis-pair approaches, respectively.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00549

DOI: 10.1021/acs.inorgchem.7b00549

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