Inorganic Chemistry
Inorganic Chemistry
5 years ago

Tuning the Photophysical Properties of Photostable Benzo[b]phosphole P-Oxide-Based Fluorophores

Tuning the Photophysical Properties of Photostable Benzo[b]phosphole P-Oxide-Based Fluorophores
Aiko Fukazawa, Chenguang Wang, Shigehiro Yamaguchi, Raúl A. Adler
Constrained 2-phenylbenzo[b]phosphole P-oxides bearing diphenylamino groups at the terminal positions as well as carbon- and silicon-bridging moieties were synthesized. The study on the impact of the bridging moieties on their photophysical properties revealed that even the silicon-brdiged compounds show outstanding photostability under irradiation with a xenon lamp, as far as the bridging moieties have sufficient steric bulkiness.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00658

DOI: 10.1021/acs.inorgchem.7b00658

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