Inorganic Chemistry
Inorganic Chemistry
3 years ago

Nitrogen–Phosphorus(III)–Chalcogen Macrocycles for the Synthesis of Polynuclear Silver(I) Sandwich Complexes

Nitrogen–Phosphorus(III)–Chalcogen Macrocycles for the Synthesis of Polynuclear Silver(I) Sandwich Complexes
Sivathmeehan Yogendra, Felix Hennersdorf, Jan J. Weigand
The synthesis of inorganic N−P(III)−Ch-based macrocycles [−PhP−NMe−PPh−Ch−]2 (Ch = S, Se) with two nitrogen, two chalcogen, and four phosphorus atoms is presented, being excellent multidentate ligands for transition metal complexation, as demonstrated by the isolation of mono-, di-, tri-, and tetranuclear silver sandwich complexes.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00141

DOI: 10.1021/acs.inorgchem.7b00141

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