Inorganic Chemistry
Inorganic Chemistry
5 years ago

Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties

Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties
Viktoria H. Gessner, Lennart T. Scharf
Metalated ylides are unique ligand systems exhibiting unusual bonding situations and strong donor abilities. Because of their two lone pairs of electrons at the ylidic carbon atom, they can function as σ- and π-donor ligands. These properties can be applied in main-group-element and transition-metal chemistry, such as for the stabilization of electron-deficient or cationic species.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00099

DOI: 10.1021/acs.inorgchem.7b00099

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.