3 years ago

Bis(N-heterocyclic olefin) Derivative: An Efficient Precursor for Isophosphindolylium Species

Bis(N-heterocyclic olefin) Derivative: An Efficient Precursor for Isophosphindolylium Species
Yongxin Li, Rakesh Ganguly, Che Chang Chong, Rei Kinjo, Bin Rao
We have synthesized isophosphindolylium species based on bis(N-heterocyclic olefin) ligands, which are fully characterized. An X-ray diffraction analysis and density functional theory study suggests the aromatic property of the PC4 five-membered ring, and the nucleophilic character of the P center was confirmed by the reaction with CuCl to afford a copper phosphenium complex.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.6b02991

DOI: 10.1021/acs.inorgchem.6b02991

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