5 years ago

Synthesis and complexation of superbulky imidazolium-2-dithiocarboxylate ligands

Synthesis and complexation of superbulky imidazolium-2-dithiocarboxylate ligands
Lionel Delaude, Guillermo Zaragoza, Tomas F. Beltran
Two NHC[middle dot]CS2 zwitterions derived from superbulky N-heterocyclic carbenes were synthesized and coordinated to Re(I) and Ru(II). The dithiocarboxylate unit of these highly flexible ligands chiefly determined the steric requirements of the imidazolium moieties, irrespective of the metal used for complexation.

Publisher URL: http://feeds.rsc.org/~r/rss/DT/~3/tYnl76vgwuI/C7DT01889D

DOI: 2017/DT/C7DT01889D

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