Dalton Transactions
Dalton Transactions
5 years ago

Synthesis, structure and dispersion interactions in bis(1,8-naphthalendiyl)distibine

Synthesis, structure and dispersion interactions in bis(1,8-naphthalendiyl)distibine
S. Schulz, C. Wolper, S. Heimann, C. Ganesamoorthy, G. Jansen, R. Haack, S. Holscher
Naph2Sb21 shows intermolecular interactions in the solid state. Quantum chemical calculations of 1 and the lighter (P, As) and heavier (Bi) congeners showed that intermolecular E[three dots, centered]E interactions (E = P, As, Sb, Bi) are dispersion dominated, while E[three dots, centered][small pi] interactions additionally contained a significant electrostatic contribution.

Publisher URL: http://feeds.rsc.org/~r/rss/DT/~3/eHtrIhu65x8/C7DT02165H

DOI: 2017/DT/C7DT02165H

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