3 years ago

Metal carbonate complexes formed through the capture of ambient O2 and CO2 by elemental metals in 1-methylimidazole: molecular Cu(CO3)(MeIm)3 and polymeric M(CO3)(MeIm)2[middle dot]2H2O (M = Co, Zn)

Metal carbonate complexes formed through the capture of ambient O2 and CO2 by elemental metals in 1-methylimidazole: molecular Cu(CO3)(MeIm)3 and polymeric M(CO3)(MeIm)2[middle dot]2H2O (M = Co, Zn)
Thomas P. Vaid, Robin D. Rogers, Steven P. Kelley
Metallic copper, zinc, and cobalt in 1-methylimidazole (MeIm) react with ambient O2 and CO2 to yield molecular Cu(CO3)(MeIm)3 and polymeric Zn(CO3)(MeIm)2[middle dot]2H2O and Co(CO3)(MeIm)2[middle dot]2H2O.

Publisher URL: http://feeds.rsc.org/~r/rss/DT/~3/FkZje2ly-AU/C7DT01787A

DOI: 2017/DT/C7DT01787A

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