Deprotonated meso-hydroxyporphyrin as a stable [small pi]-electronic anion: the building unit of an ion-pairing assembly

5 years ago

Deprotonated meso-hydroxyporphyrin as a stable [small pi]-electronic anion: the building unit of an ion-pairing assembly

Yoshifumi Sasano, Nobuhiro Yasuda, Hiromitsu Maeda

The Ni^II complex of 5-hydroxy-10,15,20-tris(pentafluorophenyl)porphyrin was synthesized as a precursor of a negatively charged [small pi]-electronic system. Deprotonation provided an anionic species as the building unit of an ion-pairing assembly in combination with an aliphatic cation.

Publisher URL: http://feeds.rsc.org/~r/rss/DT/~3/d8vpOCTaKxc/C7DT01635B

DOI: 2017/DT/C7DT01635B

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