Dalton Transactions
Dalton Transactions
5 years ago

Radical reactions of diamine bis(phenolate) vanadium(III) complexes. Solid state binding of O2 to form a vanadium(V) peroxo complex

Radical reactions of diamine bis(phenolate) vanadium(III) complexes. Solid state binding of O2 to form a vanadium(V) peroxo complex
Maria Jose Calhorda, Ana M. Coelho, Pedro Adao, Sonia Barroso, Ana M. Martins
Coupling of a V(III) diamine bis(phenolate) complex with O2 gives an [small eta]2-O2 complex when the reaction is carried out without a solvent. The latter is an intermediate in the formation of terminal V(V) oxido compounds.

Publisher URL: http://feeds.rsc.org/~r/rss/DT/~3/RmmcxsoDCh4/C7DT01699A

DOI: 2017/DT/C7DT01699A

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