3 years ago

Strongly Enhanced Photovoltaic Performance and Defect Physics of Air-Stable Bismuth Oxyiodide (BiOI)

Strongly Enhanced Photovoltaic Performance and Defect Physics of Air-Stable Bismuth Oxyiodide (BiOI)
Judith L. MacManus-Driscoll, Tonio Buonassisi, Melany Sponseller, Lana C. Lee, James Alexander Polizzotti, Vladimir Bulović, Lea Nienhaus, Vladan Stevanović, Rachel C. Kurchin, Riley E. Brandt, Moungi G. Bawendi, Tahmida N. Huq, Joel Jean, Ahmed Kursumović, Kelvin H. L. Zhang, Robert L. Z. Hoye
Bismuth-based compounds have recently gained increasing attention as potentially nontoxic and defect-tolerant solar absorbers. However, many of the new materials recently investigated show limited photovoltaic performance. Herein, one such compound is explored in detail through theory and experiment: bismuth oxyiodide (BiOI). BiOI thin films are grown by chemical vapor transport and found to maintain the same tetragonal phase in ambient air for at least 197 d. The computations suggest BiOI to be tolerant to antisite and vacancy defects. All-inorganic solar cells (ITO|NiOx|BiOI|ZnO|Al) with negligible hysteresis and up to 80% external quantum efficiency under select monochromatic excitation are demonstrated. The short-circuit current densities and power conversion efficiencies under AM 1.5G illumination are nearly double those of previously reported BiOI solar cells, as well as other bismuth halide and chalcohalide photovoltaics recently explored by many groups. Through a detailed loss analysis using optical characterization, photoemission spectroscopy, and device modeling, direction for future improvements in efficiency is provided. This work demonstrates that BiOI, previously considered to be a poor photocatalyst, is promising for photovoltaics. Bismuth oxyiodide (BiOI) is demonstrated to be defect-tolerant, with the bulk phase unchanged after 197 d in ambient air. In solar cells, up to 80% external quantum efficiency is achieved. The short-circuit current densities and power conversion efficiencies are nearly double previous reports of photovoltaics based on BiOI, as well as other recently-explored bismuth halides and chalcohalides.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/adma.201702176

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