3 years ago

Mercuration of ferrocenyl-p-tolyl sulfoxide and its conversion to 1,2-disubstituted ferrocenes

Mercuration of ferrocenyl-p-tolyl sulfoxide and its conversion to 1,2-disubstituted ferrocenes
1-(p-Tolylsulfinyl)-2-(chloromercurio)ferrocene (2) was prepared by direct mercuration of ferrocenylsulfoxide (1). This reaction can be performed at room temperature in open air. Cross-coupling reactions of compound 2 and aryl halides especially aryl iodides resulted in 1,2-disubstituted ferrocene derivatives with moderate to good yields.

Publisher URL: www.sciencedirect.com/science

DOI: S0022328X17306150

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