3 years ago![Selective synthesis of the [2-B10H9I]2− anion and some theoretical aspects of its iodination process](/image/eyJ1cmkiOiJodHRwOi8vc3RhY2thZGVtaWMuaGVyb2t1YXBwLmNvbS9pbWFnZT9pbWFnZV9pZD00NjQyNiIsImZvcm1hdCI6IndlYnAiLCJxdWFsaXR5IjoxMDAsIndpZHRoIjo1MTIsIm5vQ2FjaGUiOnRydWV9.webp)
Selective synthesis of the [2-B10H9I]2− anion and some theoretical aspects of its iodination process
New approaches to the selective synthesis of the [2-B10 H9 I]− anion have been reported based on careful control of the reaction medium acidity. The mechanism of the iodination was proposed and the regioselectivity of electrophilic substitution of the [B10 H10 ]2− anion was explained based on B3LYP-calculations of the potential energy surface of the system using the mixed basis 6-31G∗/LanL2DZ. The obtained compounds were characterized by IR and NMR (1H and 11B) spectroscopy, together with ESI-MS-spectrometry. The crystal structures of (PPh4 )2 [2-B10 H9 I] and {(PPh4 )2 [2-B10 H9 I]·2C4 H8 O2 } were determined by X-ray diffraction.
Publisher URL: www.sciencedirect.com/science
DOI: S027753871730637X
You might also like
Never Miss Important Research
Researcher is an app designed by academics, for academics. Create a personalised feed in two minutes.
Choose from over 15,000 academics journals covering ten research areas then let Researcher deliver you papers tailored to your interests each day.
Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.