3 years ago

Structural and spectroscopic studies of Au(III) chloride compounds with 7,8-benzoquinoline

Structural and spectroscopic studies of Au(III) chloride compounds with 7,8-benzoquinoline
Au(III) chloride compounds with 7,8-benzoquinoline (bqn) – [Au(bqn)Cl3] and [Au(bqn)Cl2] (bqn being deprotonated, at the C(10) carbon, monoanionic form of bqn) were studied by 1H–13C, 1H–15N HMQC and HMBC–NMR. 1H, 13C and 15N coordination shifts were discussed in relation to the molecular structures, revealing characteristic variability patterns. Analogous NMR measurements were performed for the new (bqnH+)2(AuCl4 )Cl salt, studied also by single crystal X-ray diffraction. All compounds exhibited fluorescence.

Publisher URL: www.sciencedirect.com/science

DOI: S0277538717306319

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.