3 years ago

Photochemical Single-Crystal-to-Single-Crystal (SCSC) Reactions of Anthraphane to Dianthraphane and Poly1Danthraphane

Photochemical Single-Crystal-to-Single-Crystal (SCSC) Reactions of Anthraphane to Dianthraphane and Poly1Danthraphane
Michael Wörle, Michael Solar, Nils Trapp, A. Dieter Schlüter, Marco Servalli
The photoreactivity of “anthraphane” was investigated by selecting potentially photoreactive packings from the available library of crystal structures for this compound. Packings in which the anthracene units of anthraphane are face-to-face stacked were irradiated at 465 nm, yielding via [4 + 4]-cycloaddition dianthraphane and poly1Danthraphane in quantitative yields. The photoreactivity was investigated by varying irradiation time and temperature. The thermally induced retro-cycloaddition was also demonstrated.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b01184

DOI: 10.1021/acs.cgd.7b01184

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