3 years ago

Controlled Pd(0)/Ad3P-Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with Ad3P-Coordinated Acetanilide-Based Palladacycle Complex as Initiator

Controlled Pd(0)/Ad3P-Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with Ad3P-Coordinated Acetanilide-Based Palladacycle Complex as Initiator
Qiao-Sheng Hu, Jie Dong, Hui Guo
Controlled Pd(0)-catalyzed Suzuki cross-coupling polymerizations of AB-type monomers with tris(1-adamantyl)phosphine (Ad3P) as the ligand was described. Ad3P-coordinated acetanilide-based palladacycle complex (1) was demonstrated to be an efficient initiator for controlled Suzuki cross-coupling polymerization, affording polymers with narrow Đs and well-controlled end groups. Our study provided an efficient ligand and an efficient initiator for controlled Suzuki cross-coupling polymerizations.

Publisher URL: http://dx.doi.org/10.1021/acsmacrolett.7b00759

DOI: 10.1021/acsmacrolett.7b00759

You might also like
Never Miss Important Research

Researcher is an app designed by academics, for academics. Create a personalised feed in two minutes.
Choose from over 15,000 academics journals covering ten research areas then let Researcher deliver you papers tailored to your interests each day.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.