Angewandte Chemie - International Edition
Angewandte Chemie - International Edition
5 years ago

Carbon–Fluorine Reductive Elimination from Nickel(III) Complexes

Carbon–Fluorine Reductive Elimination from Nickel(III) Complexes
Jonas Börgel, Tobias Ritter, Heejun Lee
We report a C−F reductive elimination from a characterized first-row aryl metal fluoride complex. Reductive elimination from the presented nickel(III) complexes is faster than C−F bond formation from any other characterized aryl metal fluoride complex. Fast and facile: Facile C−F reductive elimination from an arylnickel(III) fluoride complex is reported. The C−F bond reductive elimination from nickel(III) complexes presented herein is faster than the C−F bond formation from any other characterized aryl metal fluoride complex.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201701552

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