3 years ago

Pd-Catalyzed Arylperfluoroalkylation of Unactivated Olefins for the Synthesis of Heterocycles

Pd-Catalyzed Arylperfluoroalkylation of Unactivated Olefins for the Synthesis of Heterocycles
Yaofeng Yuan, Jinhua Zheng, Pan Chen, Jiajia Cheng
An efficient and highly practical palladium-catalyzed arylperfluoroalkylation of unactivated olefins is presented here. A variety of perfluoroalkylated heterocyclic derivatives can be obtained in high regioselectivity. The reaction proceeds mildly without the electronic activation of the aryl group and features high generality, low-cost fluoroalkylated sources and good functional-group compatibility.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b00598

DOI: 10.1021/acs.joc.7b00598

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