5 years ago

Electrochemical Evaluation of Titanocenes in Ionic Liquids with Non-coordinating and Coordinating Anions and Application for NH3 Synthesis

Electrochemical Evaluation of Titanocenes in Ionic Liquids with Non-coordinating and Coordinating Anions and Application for NH3 Synthesis
Tomohiko Inomata, Akira Katayama, Hideki Masuda, Tomohiro Ozawa
The Front Cover shows a firework, whose powder explosive comes from chemicals containing N atoms that are made from NH3. In their Article, A. Katayama et al. demonstrate electrochemical NH3 syntheses by using [Cp2TiCl2] in ionic liquid in a solid polymer electrolyte cell. UV-Vis/NIR spectra recorded during the electrochemical reduction of [Cp2TiCl2] reveal that it was converted to [(Cp2TiCl)2] in ionic liquid through the formation of [Cp2TiCl]. More information can be found in the Article by A. Katayama et al.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/celc.201701181

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