Angewandte Chemie - International Edition
Angewandte Chemie - International Edition
5 years ago

C3-Symmetric Tricyclo[2.2.1.02,6]heptane-3,5,7-triol

C3-Symmetric Tricyclo[2.2.1.02,6]heptane-3,5,7-triol
Günter Haufe, Peer Kirsch, Constantin-Gabriel Daniliuc, Volodymyr Kozel
The smallest tricyclic C3-symmetric triol was obtained as a racemate using a simple one-pot synthesis from readily available commercial starting materials and reagents. Classical resolution provided the “propeller-like” enantiopure triols, which have a high potential for application in asymmetric synthesis, molecular recognition, and material sciences. In their Communication (DOI: 10.1002/anie.201709279), G. Haufe et al. provide more details, including the synthesis of a chiral dopand for liquid crystals.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201710815

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