Journal of Molecular Structure
Journal of Molecular Structure
5 years ago

Two Co(II) compound constructed by phthalic acid and 3-Cl-phthalic acid: Synthesis, structure, and magnetic properties

Two Co(II) compound constructed by phthalic acid and 3-Cl-phthalic acid: Synthesis, structure, and magnetic properties
In this paper, we obtained two novel 2D layered cobalt coordination polymers, namely [(Co(o-BDC)]n (1) and (Co(3-Cl-o-BDC)]n (2), through solvothermal method with acetone as solvent based on phthalic acid (o-H2BDC) and 3-chloro-phthalic acid (3-Cl-o-H2BDC) respectively. Due to the steric hindrance effect of chloric substituent, the two ligands revealed different coordination modes. And cobalt centers of 1 and 2 showed CoO6 octahedral and CoO4 tetrahedral configurations respectively. As a result, 1 and 2 revealed different layered constructions: a 5-connected topology with 48.62 Schläfli symbol for 1, and a 4-connected topology with 44.62 Schläfli symbol for 2, respectively. Besides, Compound 1 and 2 reveal ferromagnetic and antiferromagnetic behaviors, respectively.

Publisher URL: www.sciencedirect.com/science

DOI: S0022286017314898

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.