Journal of Physical Chemistry Letters
Journal of Physical Chemistry Letters
5 years ago

Impact of Element Doping on Photoexcited Electron Dynamics in CdS Nanocrystals

Impact of Element Doping on Photoexcited Electron Dynamics in CdS Nanocrystals
Qun Zhang, Lei Zhang, Yi Luo
Element doping plays a key role in achieving desired properties of semiconductor nanocrystals. In the energy-state landscape the doping-induced localized impurity states (LIS) can bring on significant modification of photoelectrochemical effects. It is difficult to retrieve information regarding the doping-induced LIS. Here we report on such information gleaned on a prototypical system of CdS nanocrystals slightly doped with In3+, through joint observations from photoluminescence (PL) and ultrafast transient absorption (TA) spectroscopy. The nonradiative nature of the In-doping induced LIS is revealed by PL. The TA observations, with a set of control experiments, enable us to capture a picture of the photoexcited electron dynamics and unravel the photoexcited electron reservoir (PEER) effect associated with the In-doping induced band gap LIS. This work establishes a fundamental, mechanistic understanding of the significant impact of element doping on the photoexcited electron dynamics in this model system, offering useful inputs for relevant material design and applications.

Publisher URL: http://dx.doi.org/10.1021/acs.jpclett.7b02449

DOI: 10.1021/acs.jpclett.7b02449

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