Crystal Growth & Design
Crystal Growth & Design
5 years ago

Supramolecular Design of the Trinuclear Silver(I) and Copper(I) Metal Pyrazolates Complexes with Ruthenium Sandwich Compounds via Intermolecular Metal−π Interactions

Supramolecular Design of the Trinuclear Silver(I) and Copper(I) Metal Pyrazolates Complexes with Ruthenium Sandwich Compounds via Intermolecular Metal−π Interactions
Oleg A. Filippov, Lina M. Epstein, Fedor M. Dolgushin, Ivan A. Godovikov, Aleksei A. Titov, Dmitry A. Muratov, Alexander F. Smol’yakov, Elena S. Shubina
Complexation of copper(I) and silver(I) macrocyclic pyrazolates with the nonencumbered sandwiches (CpRuInd, Ind2Ru) yields infinite stacks via alternating molecules of macrocycles and sandwich compounds as one-dimensional coordination polymers with a regular structure. The general principle of supramolecular packing suggests coordination of two ligands on both faces of the macrocycle.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b01351

DOI: 10.1021/acs.cgd.7b01351

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