4 years ago

Bulk Kosterlitz–Thouless Type Molecular Superconductor β″-(BEDT-TTF)2[(H2O)(NH4)2Cr(C2O4)3]·18-crown-6

Bulk Kosterlitz–Thouless Type Molecular Superconductor β″-(BEDT-TTF)2[(H2O)(NH4)2Cr(C2O4)3]·18-crown-6
Hiroki Akutsu, Yasuhiro Nakazawa, Jordan R. Lopez, Lee Martin, Shusaku Imajo
A new molecular superconductor, β″-(BEDT-TTF)2[(H2O)(NH4)2Cr(C2O4)3]·18-crown-6, has been synthesized from the organic donor molecule BEDT-TTF with the anion Cr(C2O4)33−. The crystal structure consists of conducting organic layers of BEDT-TTF molecules which adopt the β″ packing motif (layer A), layers of NH4+ and Λ-Cr(C2O4)33− (layer B), layers of (H2O)(NH4)18-crown-6 (layer C), and layers of NH4+ and Δ-Cr(C2O4)33− (layer D) which produce a structure with a repeating pattern of ABCDABCDA.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02171

DOI: 10.1021/acs.inorgchem.7b02171

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