Inorganic Chemistry
Inorganic Chemistry
5 years ago

Thermal Iodine Loss Cascade of W5I16

Thermal Iodine Loss Cascade of W5I16
Hans-Jürgen Meyer, Markus Ströbele
Thermal decomposition of W5I16 at low iodine pressure passes through a number of cluster compounds (W5I15, W5I13·xI2, β-W5I12, and W5I11) under the release of iodine. At higher iodine pressures, only one intermediate compound (α-W5I12) was found. The crystal structure of W5I11 reveals a nice relationship to its thermal transformation product W6I12.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02417

DOI: 10.1021/acs.inorgchem.7b02417

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