Inorganic Chemistry
Inorganic Chemistry
4 years ago

Hexalanthanide Complexes as Molecular Precursors: Synthesis, Crystal Structure, and Luminescent and Magnetic Properties

Hexalanthanide Complexes as Molecular Precursors: Synthesis, Crystal Structure, and Luminescent and Magnetic Properties
Marin Puget, Guillaume Calvez, Haiyun Yao, Yan Suffren, Olivier Guillou, Christophe Lescop, Kevin Bernot, Carole Daiguebonne
Reaction of hexanuclear octahedral molecular precursors with a 3-chlorobenzoate ligand affords an unprecedented family of isostructural polylanthanide complexes with the general chemical formula {[Ln6(μ3-OH)2(H2O)2(NO3)2(3-cb)14]·(CH3CN)4}, where 3-cb- stands for 3-chlorobenzoate and Ln = Eu, Tb, Dy, Ho, Er, or Y. The crystal structure, solubility, and magnetic and luminescent properties of these complexes have been studied. The luminescent properties evidence that the composition of the hexalanthanide precursor is preserved during the synthetic process.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02452

DOI: 10.1021/acs.inorgchem.7b02452

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