Angewandte Chemie - International Edition
Angewandte Chemie - International Edition
5 years ago

Transition Metal pi-Ligation of a Tetrahalodiborane

Rian D. Dewhurst, Eduard Matito, Holger Braunschweig, J. Oscar C. Jimenez-Halla, Jonas Muessig
The reaction of tetraiododiborane (B2I4) with trans- [Pt(BI2)I(PCy3)2] led to isolation of the diplatinum(II) complex [{(Cy3P)(I2B)Pt}2(μ2:h3:h3-B2I4)], supported by the bridging diboranyl dianion ligand [B2I4]2-. The complex is the first transition metal complex of a diboranyl dianion, as well as the first example of intact coordination of a B2X4 (X = halide) unit of any type to a metal center.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201709515

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