Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

One-Step Assembly of Visible and Near-Infrared Emitting Metallacrown Dimers Using a Bifunctional Linker

One-Step Assembly of Visible and Near-Infrared Emitting Metallacrown Dimers Using a Bifunctional Linker
Tu N. Nguyen, Ivana Martinić, Chun Y. Chow, Jeff W. Kampf, Vincent L. Pecoraro, Evan R. Trivedi, Stéphane Petoud, Svetlana V. Eliseeva
GaIII/LnIII metallacrown (MC) complexes with a dimeric structure have been designed, synthesized and characterized. The presence of the bridge in the [LnGa4]2 allows for a broad variety of functionalization with chemical groups of different nature through carboxylate substitution. Moreover, the MC scaffold in [LnGa4]2 is able to efficiently sensitize the characteristic emission of Nd, Pr, Sm, Tb, Dy, Ho, Er and Yb ions in the visible and/or NIR ranges in the solid state. More information can be found in the Communication by S. V. Eliseeva, S. Petoud, V. L Pecoraro et al. (DOI: 10.1002/chem.201703911).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201705225

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