Chemistry - A European Journal
Chemistry - A European Journal
4 years ago

Frontispiece: Aryl Transfer Selectivity in Metal-Free Reactions of Unsymmetrical Diaryliodonium Salts

Frontispiece: Aryl Transfer Selectivity in Metal-Free Reactions of Unsymmetrical Diaryliodonium Salts
David R. Stuart
Unsymmetrical diaryliodonium salts participate in a wide range of metal-free transformations that involve λ3-iodanes, λ3-iodane radical anions, aryl radicals, and arynes. Despite the diversity of these reactive intermediates, general trends for aryl transfer selectivity have been organized on the basis of electronic and steric effects of the iodonium reagent's aryl groups. For more information see the Minireview by D. R. Stuart on page 15852 ff.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201786362

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