Inorganic Chemistry
Inorganic Chemistry
5 years ago

Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge

Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge
Jiang-Gao Mao, Fang Kong, Chun-Li Hu, Jiang-He Feng, Hou-Ping Xia
The first lithium fluoride tellurite, namely, Li7(TeO3)3F (P63), was synthesized successfully by solid-state reactions. Its structure features a novel 3D anionic framework of [Li7O9F]12− composed of LiO3F and LiO4 tetrahedra with 1D hexagonal tunnels of 12-membered rings along the c-axis, where all “isolated” ψ-TeO3 tetrahedra are located. Powder Li7(TeO3)3F exhibits large SHG responses (3× KDP @1064 nm, 0.2× BBO @532 nm) and a large LDT (73 × AGS).

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02670

DOI: 10.1021/acs.inorgchem.7b02670

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