4 years ago

Insertion of a Transient Tin Nitride into Carbon–Carbon and Boron–Carbon Bonds

Insertion of a Transient Tin Nitride into Carbon–Carbon and Boron–Carbon Bonds
R. David Britt, Lizhi Tao, Troy A. Stich, Philip P. Power, Marilyn M. Olmstead, Shuai Wang
Photolysis of a diethyl ether solution of [AriPr4Sn(μ-N3)]2 for ca. 16 h yielded an azepinyl-substituted insertion product, [C6H3-2-(C6H3-2,6-iPr2)-6-(C6H3N-3,7-iPr2)Sn]2. The proposed mechansim suggests a very reactive [−SnIV≡N] intermediate, which coexists with its nitrene [−SnII−N] and nitridyl [−SnIII═N·] isomers, was generated during the reaction.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02413

DOI: 10.1021/acs.inorgchem.7b02413

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